.2. according to Regulation (EC) No 907/2006 (REACH) SECTION : Identification of the substance/mixture and of the company/undertaking.. Product identifier substance / mixture mixture.3..4. Number PN035b/2009 Other names of the mixture BISIL Thermo Relevant identified uses of the substance or mixture and uses advised against Intended use of the mixture Silicone top coating for steel and cast iron substrates with heat resistance quality up to 700 C. The use descriptors SU 22 SU 7 PC 9a PROC 0 PROC 3 ERC 5 Professional uses: Public domain (administration, education, entertainment, services, craftsmen) General manufacture, e.g. machinery, equipment, vehicles, other transport equipment Coatings and paints, thinners, paint removers Roller application or brushing Treatment of articles by dipping and pouring Industrial use resulting in inclusion into or onto a matrix Not recommended use of the mixture The product should not be used in ways other then those referred in Section. Details of the supplier of the safety data sheet Supplier Name or trade name BIOPOL paints s.r.o. Address Okřínek č.p.29, Okřínek, 290 0 Czech Republic Telephone +420 325653080 Fax +420 325653080 E-mail info@biopol.cz Web address www.biopol.cz Manufacturer Name or trade name BIOPOL paints s.r.o. Address Okřínek č.p.29, Okřínek, 290 0 Czech Republic Telephone +420 325653080 Fax +420 325653080 E-mail info@biopol.cz Web address www.biopol.cz Competent person responsible for the safety data sheet Name Vladislav Čáp, Ing. E-mail cap@biopol.cz Emergency telephone number Poisoning information centre, Na Bojišti, Praha, Czech Republic, Tel.: non-stop +420 224 99 293 or +420 224 95 402, Information on health risks only - acute poisoning of humans and animals SECTION 2: Hazards identification 2.. Classification of the substance or mixture Classification of the mixture in accordance with Regulation (EC) No 272/2008 The mixture is classified as dangerous. Flam. Liq. 3, H226 Asp. Tox., H304 Acute Tox. 4, H32, H332 Skin Irrit. 2, H35 Eye Irrit. 2, H39 STOT SE 3, H335 STOT RE 2, H373 Page / Made in SBLCore 205 (5.0.29) www.sblcore.com
according to Regulation (EC) No 907/2006 (REACH) The classification of the mixture according to Directive 999/45/EC The mixture is classified as dangerous. Flammable: R 0 Harmful: Xn; R 20/2 Irritant: Xi; R 36/37/38 Full text of all classifications, H-phrases and R-phrases is given in the section 6. 2.2. The most serious adverse physico-chemical effects Flammable liquid and vapour. The most serious adverse effects on human health and the environment May be fatal if swallowed and enters airways. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure. Label elements Warning symbol Signal word Danger Hazardous substances xylen Hazard statements H226 H304 H32 H35 H39 H332 H335 H373 Flammable liquid and vapour. May be fatal if swallowed and enters airways. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure. Instructions for safe handling P0 If medical advice is needed, have product container or label at hand. P02 Keep out of reach of children. P03 Read label before use. P20 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P24 Use explosion-proof electrical equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P273 Avoid release to the environment. P280 Wear protective gloves. P302+P352 IF ON SKIN: Wash with plenty of water. P32 Specific treatment (see? on this label). P362 Take off contaminated clothing. P370+P378 In case of fire: Use carbon dioxide to extinguish. P39 Collect spillage. P403+P235 Store in a well-ventilated place. Keep cool. P50 Dispose of contents/container to local regulations. Page 2/ Made in SBLCore 205 (5.0.29) www.sblcore.com
2.3. according to Regulation (EC) No 907/2006 (REACH) Density >.5 g/cm 3 VOC 0.43 kg/kg TOC max.0.400.kg/kg Dry matter 40 % volume Max. VOC content in the product in its ready to use condition max.500g/l Requirements for child-resistant fastenings and tactile warning of danger Container has to be fitted with a tactile warning of danger.packaging should be equipped with child-resistant top. Other hazards Substance does not meet the criteria for PBT or vpvb in accordance with Annex XIII of Regulation (EC) no. 272/2008. SECTION 3: Composition/information on ingredients 3.2. Mixtures Chemical characterization Mixture of substances specified below and additives. Mixture contains these hazardous substances and substances with the highest permissible concentration in the working environment Identification numbers Name of the substance Content in % weight Classification according to Directive 67/548/EEC Classification according to Regulation (EC) No 272/2008 Note Index: 60-022-00-9 CAS: 330-20-7 ES: 25-535-7 xylen <40 R 0 Xn; R 20/2 Xi; R 36/37/38 Flam. Liq. 3, H226 Asp. Tox., H304 Acute Tox. 4, H32, H332 Skin Irrit. 2, H35 Eye Irrit. 2, H39 STOT SE 3, H335 STOT RE 2, H373 The full text of all standard phrases and guidelines is specified in Section 6. SECTION 4: First aid measures 4.. Description of first aid measures If any health problems are manifested or if in doubt, inform a doctor and show him information from this Safety Data Sheet. If unconscious, put the person in the stabilized (recovery) position on his side with his head slightly bent backwards and make sure that airways are free; never induce vomiting. If the person vomits by himself, make sure that the vomit is not inhaled. In life threatening conditions first of all provide resuscitation of the affected person and ensure medical assistance. Respiratory arrest - provide artificial respiration immediately. Cardiac arrest - provide indirect cardiac massage immediately. Inhalation Terminate the exposure immediately and move the affected person to fresh air (remove contaminated clothes). Protect the person against growing cold. Ensure medical treatment considering the frequent need of further observation for at least 24 hours. Skin contact Remove contaminated clothes. Wash the affected area with plenty of water, lukewarm if possible. Soap, soap solution or shampoo should be used if there is no skin injury. Provide medical treatment. Eye contact Immediately flush eyes with running water, open eyelids (even violently); if a victim has contact lenses, remove them immediately. Rinse for at least 0 minutes. Ensure medical, preferably professional treatment. Ingestion DO NOT INDUCE VOMITING! If the affected person vomits, make sure to prevent inhalation of the vomit (as there is a danger of lung damage after inhalation of these liquids in the airways also in infinitesimal amount). Provide medical treatment considering the frequent need of further observation for at least 24 hours. Bring an original container with the label and the Safety Data Sheet of the given substance as appropriate. 4.2. Most important symptoms and effects, both acute and delayed Inhalation Possible irritation of airways, cough, headache. Skin contact Painful reddening, irritation. Eye contact Not expected. Ingestion Irritation, nausea. 4.3. Indication of any immediate medical attention and special treatment needed Symptomatic treatment. Page 3/ Made in SBLCore 205 (5.0.29) www.sblcore.com
according to Regulation (EC) No 907/2006 (REACH) SECTION 5: Firefighting measures 5.. Extinguishing media Suitable extinguishing media alcohol-resistant foam, carbon dioxide, powder, water spray jet, water mist 5.2. 5.3. Unsuitable extinguishing media water - full jet Special hazards arising from the substance or mixture Fire produces heavy, black smoke, with potential development of carbon monoxide and dioxide and other toxic gases. Inhalation of hazardous degradation (pyrolysis) products may cause serious health damage. Advice for firefighters Směs je hořlavá.use a self-contained breathing apparatus and full-body protective clothing. Uzavřené nádoby se směsí v blízkosti požáru chlaďte vodou. Do not allow run-off of contaminated fire extinguishing material to enter drains or surface and ground water. SECTION 6: Accidental release measures 6.. Personal precautions, protective equipment and emergency procedures Remove all ignition sources; provide sufficient ventilation. Use personal protective equipment for work. Follow the instructions in Sections 7 and 8. 6.2. Environmental precautions Prevent contamination of the soil and entering surface or ground water. Do not allow to enter drains. 6.3. 6.4. Methods and material for containment and cleaning up Rozlitou směs pokryjte vhodným (nehořlavým) absorbujícím materiálem (písek, křemelina, zemina a jiné vhodné absorpční materiály), shromážděte v dobře uzavřených nádobách a odstraňte dle oddílu 3. Collected material should be disposed of in accordance with locally valid regulations. Při úniku velkých množství směsi informujte hasiče a odbor životního prostředí Obecního úřadu obce s rozšířenou působností. Po odstranění směsi umyjte kontaminované místo velkým množstvím vody nebo jiného vhodného čistícího prostředku. Do not use solvents. Reference to other sections 7, 8 and 3. SECTION 7: Handling and storage 7.. Precautions for safe handling Prevent formation of gases and vapours in flammable or explosive concentrations and concentrations exceeding the occupational exposure limits. Směs používejte jen v místech, kde nepřichází do styku s otevřeným ohněm a jinými zápalnými zdroji. Nekuřte. Protect against direct sunlight. Electrostatic charge may be formed during use; use only earthed piping (tubing) when repumping. Use of antistatic clothes and footwear is recommended. Use non-sparking tools. Do not inhale gases and vapours. Prevent contact with skin and eyes. Use personal protective equipment as per Section 8. Dbejte na platné právní předpisy o bezpečnosti a ochranně zdraví. 7.2. Conditions for safe storage, including any incompatibilities Store in tightly closed containers in cold, dry and well ventilated areas designated for this purpose. Do not expose to sunlight. Storage class Content Type of packaging Material of package 3B - Flammable liquids (VbF hazard class A III) 0,7 kg, 3,5 kg, 8kg kovový obal FE (40), Steel (Metals) 40 7.3. Storage temperature min 5 C, max 35 C The specific requirements or rules relating to the substance/mixture Solvent vapours are heavier than air and accumulate especially near the floor where they may form an explosive mixture with the air. Specific end use(s) Přechovávejte pouze v nádobách, které odpovídají originálnímu balení. Dbejte pokynů uvedených na etiketě přípravku. FE Page 4/ Made in SBLCore 205 (5.0.29) www.sblcore.com
according to Regulation (EC) No 907/2006 (REACH) SECTION 8: Exposure controls/personal protection 8.. Control parameters Směs obsahuje látky, pro něž jsou stanoveny (NV č.36/2007 Sb., v platném znění) následující koncentrační limity v pracovním prostředí (nejvyšší přípustný expoziční limit=pel; nejvyšší přípustná koncentrace v pracovním ovzduší=npk-p). 8.2. Exposure controls Follow usual measures for health protection at work and especially for good ventilation. This can be achieved only by local suction or efficient general ventilation. If exposure limits cannot be observed in this mode, suitable protection of airways must be used. Do not eat, drink and smoke during work. Wash your hands thoroughly with water and soap after work and before breaks for a meal and rest. Eye and face protection Protective goggles or face shield (based on the nature of the work performed). Skin protection Hand protection: Protective gloves resistant against the product. Observe recommendations of the particular manufacturer of the gloves in the choice of their appropriate thickness, material and permeability. Use barrier creams for skin protection, they should however not be applied once exposure has occurred. Observe other recommendations of the manufacturer. Other protection: Protective antistatic clothing made of natural fibres (cotton) or synthetic fibres resistant against elevated temperatures. Contaminated skin should be washed thoroughly. Respiratory protection Mask with a filter against organic vapours or a self-contained breathing apparatus as appropriate if exposure limit values of toxic substances are exceeded or in a poorly ventilated environment. Thermal hazard Restriction of the environment exposure Observe usual measures for protection of the environment, see Section 6.2. SECTION 9: Physical and chemical properties 9.. Information on basic physical and chemical properties Appearance Physical state Color Odour Odour threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limits Explosive limits bottom upper Vapour pressure Vapour density Relative density Solubility(ies) solubility in water solubility in fats v org.rozp.: Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity the time of flow Explosive properties Oxidising properties Nejsou barevná viskózní kapalina liquid at 20 C dle použitého pigmentu po xylenu 38-45 C >23 C hořlavá kapalina xylen 0.7 obj % xylen 4.4 %.73kPa (xylen) at 20 C xylen: 3,66 (vzduch =) nerozpustný rozpustný rozpustný, zejm.nepolárních: xylen, lakový benzin >450 C Ford prům.4.0mm >45s nejsou Page 5/ Made in SBLCore 205 (5.0.29) www.sblcore.com
9.2. according to Regulation (EC) No 907/2006 (REACH) Other information Density Auto-ignition temperature Content of organic solvents (VOC) Total organic carbon (TOC) Solid content (dry matter) Max. VOC content in the product in its ready to use condition >.5 g/cm 3 at 20 C 0.43 kg/kg max.0.400.kg/kg 40 % volume max.500g/l SECTION 0: Stability and reactivity 0.. Reactivity The mixture is flammable. 0.2. Chemical stability Při normálních podmínkách je směs stabilní. 0.3. Possibility of hazardous reactions Při normálních podmínkách je směs stabilní. 0.4. Conditions to avoid Za normálního způsobu použití je směs stabilní, k rozkladu nedochází. Protect against flames, sparks, overheating and against frost. 0.5. 0.6. Incompatible materials Protect against strong acids, bases and oxidizing agents. Thereby a dangerous exothermic reaction will be prevented. Hazardous decomposition products Not developed under normal uses. Dangerous products are formed at high temperature and in fire, such as carbon monoxide and carbon dioxide, heavy smoke and nitrogen oxides. SECTION : Toxicological information.. Information on toxicological effects No toxicological data is available for the mixture. Acute toxicity Route of exposure oral dermal xylen Route of exposure oral inhalation (vapor) Parameter LD 50 LD 50 Parameter LD 50 LC 50 Method Method Value 4300 mg/kg <700 mg/kg Value >2000-5000 mg/kg >0-20 mg/l Time of exposure Time of exposure Species rat rabbit Species human human May be fatal if swallowed and enters airways. Harmful in contact with skin. Harmful if inhaled. Corrosion/skin irritation Causes skin irritation. Serious eye damage / eye irritation Causes serious eye irritation. Respiratory / skin sensitization Based on available data the classification criteria are not met. Germ cells mutagenicity Based on available data the classification criteria are not met. Carcinogenicity Based on available data the classification criteria are not met. Reproductive toxicity Based on available data the classification criteria are not met. Toxicity for specific target organ - single exposure May cause respiratory irritation. Toxicity for specific target organ - repeated exposure Sex Sex Determining the value of Determining the value of Source Source Page 6/ Made in SBLCore 205 (5.0.29) www.sblcore.com
according to Regulation (EC) No 907/2006 (REACH) Based on available data the classification criteria are not met. Aspiration hazard May be fatal if swallowed and enters airways. SECTION 2: Ecological information 2.. Toxicity 2.2. 2.3. 2.4. 2.5. 2.6. Acute toxicity Parameter LC 50 xylen Parameter Method Method Value 3.3-4.093 mg/l Value Time of exposure 96 hour Time of exposure Species fishes Species LC 50 26.7 mg/l 96 hour invertebrates (Pimephales promelas) LC 50 6.9 mg/l 96 hour fishes (Carassius auratus) The product contains no substances with an effect against active action of microorganisms. Persistence and degradability Směs je biologicky rozložitelná. Bioaccumulative potential Insignificant. Mobility in soil Other adverse effects Environme nt Environme nt freshwater The product is soluble and mobile in water and soil. Contamination of water courses may occur in case of rain. Results of PBT and vpvb assessment Směs není hodnocena jako PBT nebo jako vpvb. Determining the value of Determining the value of Source Source SECTION 3: Disposal considerations Hazard of environmental contamination; remove waste in accordance with local and/or national regulations. 3.. Waste treatment methods Proceed in accordance with valid regulations on waste disposal. Any unused product and contaminated packaging should be put in labelled containers for waste collection and submitted for disposal to an authorised person for waste removal (specialized company) authorised for such activity. Do not empty unused product in drainage systems. The product must not be disposed of with municipal waste. Empty containers may be used at waste incinerators to produce energy or deposited in a dump with appropriate classification. Perfectly cleaned containers can be submitted for recycling. Legislation of waste Council Directive 75/442/EEC on waste, as last amended. Council Directive 9/689/EEC on hazardous waste, as last amended. Decision 94/3/EC establishing a list of wastes, as last amended. Code of type of waste 080 Type of waste waste paint and varnish containing organic solvents or other dangerous substances Subgroup of waste wastes from MFSU and removal of paint and varnish WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS Waste group (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS Another code of type of waste 500 Type of waste packaging containing residues of or contaminated by dangerous substances Subgroup of waste packaging (including separately collected municipal packaging waste) WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE Waste group CLOTHING NOT OTHERWISE SPECIFIED Another code of type of waste 000 Type of waste wastes from mineral metalliferous excavation Subgroup of waste wastes from mineral excavation WASTES RESULTING FROM EXPLORATION, MINING, QUARRYING, AND PHYSICAL AND Waste group CHEMICAL TREATMENT OF MINERALS Page 7/ Made in SBLCore 205 (5.0.29) www.sblcore.com
Code of type of waste packaging Type of waste Subgroup of waste Waste group SECTION 4: Transport information 4.. UN number UN 263 4.2. 4.3. 4.4 4.5. 4.6. 4.7. according to Regulation (EC) No 907/2006 (REACH) UN proper shipping name PAINT Transport hazard class(es) 3 Flammable liquids Packing group III - Less hazardous substances Environmental hazards Special precautions for user Reference in Sections 4 to 8. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Additional information The hazard identification number UN number Classification code Safety signs 5004 metallic packaging packaging (including separately collected municipal packaging waste) WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED F 3 30 263 (Kemler Code) Road transport ADR Special provision 63, 640E, 650 Limited amount 5 L Extracted amounts E Packaging Packaging instruction P00, IBC03, LP0, R00 Special provision for packaging PP, Packing provisions MP9 Portable tanks and containers for open stored materials Guidelines Special provision Tanks ADR Code of the tank Vehicles for the transport in tanks Transport category Tunnel restriction code Special provision for transport of pieces service T2 TP, TP29 LGBF FL 3 D/E V2 S2 Page 8/ Made in SBLCore 205 (5.0.29) www.sblcore.com
according to Regulation (EC) No 907/2006 (REACH) Railway transport - RID Special provision 63, 640E, 650 Packaging Packaging instruction P00, IBC03, LP0, R00 Special provision for packaging PP, Packing provisions MP9 Portable tanks and containers for open stored materials Guidelines T2 Special provision TP, TP29 Tanks RID Code of the tank LGBF Transport category 3 Special provision for transport of pieces W 2 Air transport - ICAO/IATA Packing instructions for limited amount of Packing instruction passenger Packing instruction cargo Marine transport - IMDG EMS (emergency plan) MFAG Marine pollution Y344 355 366 F-E, S-E 30 Yes SECTION 5: Regulatory information 5.. Safety, health and environmental regulations/legislation specific for the substance or mixture Nařízení Evropského parlamentu a Rady (ES) č. 907/2006 ze dne 8. prosince 2006 o registraci, hodnocení, povolování a omezování chemických látek, o zřízení Evropské agentury pro chemické látky, o změně směrnice 999/45/ES a o zrušení nařízení Rady (EHS) č. 793/93, nařízení Komise (ES) č. 488/94, směrnice Rady 76/769/EHS a směrnic Komise 9/55/EHS, 93/67/EHS, 93/05/ES a 2000/2/ES v platném znění. Nařízení Evropského parlamentu a Rady (ES) č. 272/2008 ze dne 6. prosince 2008 o klasifikaci, označování a balení látek a směsí, o změně a zrušení směrnic 67/548/EHS a 999/45/ES a o změně nařízení (ES) č. 907/2006 v platném znění. Směrnice 67/548/EHS v platném znění a 999/45/ES v platném znění. Zákon č. 350/20 Sb., o chemických látkách a chemických směsích a o změně některých zákonů (chemický zákon). Vyhláška č. 402/20 Sb., o hodnocení nebezpečných vlastností chemických látek a chemických směsí a balení a označování nebezpečných chemických směsí. Nařízení vlády č. 36/2007 Sb., kterým se stanoví podmínky ochrany zdraví při práci v platném znění. Zákon č. 372/20 Sb., o zdravotních službách a podmínkách jejich poskytování (zákon o zdravotních službách). Zákon č. 258/2000 Sb., o ochraně veřejného zdraví v platném znění. Vyhláška č. 45/202 Sb., o přípustné úrovni znečišťování a jejím zjišťování a o provedení některých dalších ustanovení zákona o ochraně ovzduší. Vyhláška č. 246/200 Sb., o požární prevenci. Zákon č. 85/200 Sb., o odpadech a jeho prováděcí předpisy v platném znění. Zákon č. 20/202 Sb., o ochraně ovzduší. Nařízení vlády č. 35/2009, kterým se mění nařízení vlády č. 94/200 Sb., kterým se stanoví technické požadavky na aerosolové rozprašovače, ve znění nařízení vlády č. 305/2006 Sb. Vyhláška č. 432/2003 Sb., kterou se stanoví podmínky pro zařazování prací do kategorií, limitní hodnoty ukazatelů biologických expozičních testů, podmínky odběru biologického materiálu pro provádění biologických expozičních testů a náležitosti hlášení prací s azbestem a biologickými činiteli. 5.2. Chemical safety assessment More information Nařízení Evropského parlamentu a Rady (ES) č. 907/2006 ze dne 8.prosince 2006 o registraci, hodnocení, povolování a omezování chemických látek, o zřízení Evropské agentury pro chemické látky, o změně směrnice 999/45/ES a o zrušení nařízení Rady (EHS) č. 793/93, neřízení Komise (ES) č. 488/94, směrnice Rady 76/769/EHS a směrnic Komise 9/55/EHS, 93/67/ES, 93/05/ES a 2000/2/ES v platném znění. Nařízení Evropského parlamentu a Rady (ES) č.272/2008 ze dne 6. prosince 2008 o klasifikaci, označování a balení látek a směsí, o změně a zrušení směrnic 67/548/EHS a 999/45/ES a o změně nařízení (ES) č. 907/2006 v platném znění. Směrnice 67/548/EHS v platném znění a 999/45/ES v platném znění. Zákon č. 350/20 Sb., o chemických látkách a chemických směsích a o změně některých zákonů (chemický zákon).vyhláška č. 402/20 Sb., o hodnocení nebezpečných vlastností chemických látek a chemických směsí a balení a označování nebezpečných chemických směsí. 6. SECTION 6: Other information A list of standard risk phrases used in the safety data sheet H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H32 Harmful in contact with skin. Page 9/ Made in SBLCore 205 (5.0.29) www.sblcore.com
H35 H39 H332 H335 H373 according to Regulation (EC) No 907/2006 (REACH) Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure. Guidelines for safe handling used in the safety data sheet P0 If medical advice is needed, have product container or label at hand. P02 Keep out of reach of children. P03 Read label before use. P20 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P24 Use explosion-proof electrical equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P273 Avoid release to the environment. P280 Wear protective gloves. P302+P352 IF ON SKIN: Wash with plenty of water. P32 Specific treatment (see? on this label). P362 Take off contaminated clothing. P370+P378 In case of fire: Use carbon dioxide to extinguish. P39 Collect spillage. P403+P235 Store in a well-ventilated place. Keep cool. P50 Dispose of contents/container to local regulations. List of R-phrases used in the safety data sheet R 0 Flammable. R 20/2 Harmful by inhalation and in contact with skin. R 36/37/38 Irritating to eyes, respiratory system and skin. Other important information about safety of human health The product must not be - unless specifically approved by the manufacturer/importer - used for purposes other than as per Section. The user is responsible for adherence to all related health protection regulations. Key to abbreviations and acronyms used in the safety data sheet ADR European agreement concerning the international carriage of dangerous goods by road BCF Bioconcentration Factor CAS Unique Numeric Identifier used in chemistry for chemical substances CLP Classification, Labelling and Packaging DNEL Derived no-effect level EC50 Concentration of a substance when it is affected 50% of the population EINECS European Inventory of Existing Commercial Chemical Substances Ems Emergency plan ErC50 Environmental Release category ES Identification code for each substance listed in EINECS IATA International Air Transport Association IBC International Code For The Construction And Equipment of Ships Carrying Dangerous Chemicals IC50 Concentration causing 50 % blockade ICAO International Civil Aviation Organization IMDG International Maritime Dangerous Goods Transport LC50 Lethal concentration of a substance in which it can be expected death of 50% of the population LD50 Lethal dose of a substance in which it can be expected death of 50% of the population LOAEC Lowest observed adverse effect concentration LOAEL Lowest observed adverse effect level Log Kow Octanol-water partition coefficient MARPOL International Convention for the Prevention of Pollution From Ships MFAG First Aid Manual NOAEC No observed adverse effect concentration Page 0/ Made in SBLCore 205 (5.0.29) www.sblcore.com
NOAEL NOEC NOEL OEL PBT PEL PNEC REACH RID UN UVCB VOC vpvb according to Regulation (EC) No 907/2006 (REACH) No observed adverse effect level No observed effect concentration No observed effect level Occupational Exposure Limits Persistent,Bioaccumulative and Toxic Permissible Exposure Limit Predicted no-effect concentration Registration, Evaluation and Restriction of chemicals (EP and Council Regulation (EC) No.907/2006) Agreement on the transport of dangerous goods by rail Four-digit code reflecting the characteristics of substances or mixtures in transport Substances of unknown or variable composition, complex reaction products or biological materials Volatile organic compounds Very Persistent and very Bioaccumulative Acute Tox. Asp. Tox. Eye Irrit. Flam. Liq. Skin Irrit. STOT RE STOT SE Acute toxicity Aspiration hazard Eye irritation Flammable liquid Skin irritation Specific target organ toxicity - repeated exposure Specific target organ toxicity - single exposure Training guidelines Seznámit pracovníky s doporučeným způsobem použití, povinnými ochrannými prostředky, první pomocí a zakázanými manipulacemi se směsí. Recommended restrictions of use Information about the sources of data used to compile the Safety Data Sheet Nařízení Evropského parlamentu a Rady (ES) č.907/2006 (REACH) v platném znění, Nařízení Evropské komise a Rady (ES) č.272/2008 v platném znění, Nařízení Komise (EU) č.453/200, směrnice 67/548/EHS ve znění pozdějších předpisů a 999/45/ES, Nařízení Komise (EU) č. 286/20, kterým se pro účely přizpůsobení vědeckotechnickému pokroku mění nařízení Evropského parlamentu a Rady (ES) č. 272/2008 o klasifikaci, označování a balení látek a směsí, Zákon č.350/20 Sb., o chemických látkách a chemických směsích v platném znění, Vyhláška 402/20 Sb. o hodnocení nebezpečných vlastností chemických látek a chemických směsí a balení a označování nebezpečných chemických směsí, údaje od společnosti nebo podniku, databáze nebezpečných látek. Publikace "Zásady pro poskytování první pomoci při expozici chemickým látkám" (doc. MUDr. Daniela Pelclová, CSc., MUDr. Alexandr Fuchs, CSc., MUDr. Miroslava Hornychová, CSc., MUDr. Zdeňka Trávníčková, CSc., Jiřina Fridrichovská, prom. chem.) Statement The safety data sheet provides information aimed at ensuring safety and health protection at work and environmental protection. The provided information corresponds to the current status of knowledge and experience and complies with valid legal regulations. The information should not be understood as guaranteeing the suitability and usability of the product for a particular application. Page / Made in SBLCore 205 (5.0.29) www.sblcore.com